Frozen Banshee is a good candidate to get 6* next. But make sure she has sufficient accuracy. As a rule of thumb dungeon level x 10. Maybe one accuracy set is not enough to achieve that. She is great at Clan Boss and Dragon and helps you to get better gear for your champs that way.
In general your roster is to small right now. You don't have a good healer, what is quite important for your progression in dungeons. The enemies, not only the boss, but the waves as well, hit back in higher dungeon levels. You definetly need some healing and defense. The only champ that has some kind of healing mechanic is Achak, but his heals are more like a nice addition to your team. He will not make a champ survive that is heavily injured with only a few % hp left. An Apothecary would fit great to your account, or Rector Drath, or Scyl, just waite 6 months 😺 and you get her fro free as log-in reward.
From the champs you allready own, F. banshee, Samar, Royal Guard and Warmaiden are worth 6*. You can skip Warmaiden if you find a better champ for AoE def decreasing (Stag Knight, Dhukk, Armina and some others), but Warmaiden is easy to book. You can farm copies of here in campaign and use them, so Warmaiden will have a 100% debuff-chance easily, while all the epics that can do the same job better than her are harder to max out.
And do yourself a big favour and forget about 3* the campaign right now. 4 champs worth lvl 60 allready, 12-3 brutal is your place to be. You can do the campaign 3* mission easily, when you have a bunch of lvl 60 champs and you can switch your 2-champ-team according to the affinities and enemie moves in the actual stage. Wasting energy and time to try that now (to early) will not do anything for your progression.