He's valuable early because he brings a pretty reliable ATK down. Most rare champs have their ATK down on a cooldown move, which means if it's ever resisted, you're stuck waiting another three turns before you can try again. Since his is on an A1, even if it is resisted one turn, you can still land it the next. The HP burn is nice as well, but that's more icing than anything else.
So, does he remain relevant? Not really. You'll get epic or legendary champs with pretty consistent ATK down and other tools as well.
That said, whether he's worth 6-starring or not depends entirely on the rest of your champs, and where you are in terms of progression. If the thing stopping you from getting top chest in Brutal, or potentially even Nightmare CB is the lack of ATK down, then sure, he'd be worth it. But otherwise, I'd probably focus on others - Geomancer for example will likely be far more useful.
On another note - you say it is very slow to rank people up. That makes me question how you are currently doing it? If ranking champs to 6* is your main priority, you should easily be able to get one a week, possibly even two. Are you farming Brutal 12-3 with a solo champ, and quickly? If not, that should probably be your number one priority.