Speaking from experience, I focused on Arena before Clan Boss, and the peeps telling you that focusing on CB first will advance your account substanially faster are 100% correct. However, I thoroughly enjoy arena, and actively play all three modes. I especially like 3v3 (Rare indeed) because it is a 3-part puzzle. Maxing GH Bonuses early will help you with builds across the entire game.
CP is right that Rathalos should outperform Kael as your nuker, but they are both attack based and therefore squishy. Valla is one of the best epic defense based nukers in the game. She self-buffs a Shield and an Inc Def buff; She removes shields from the whole enemy team, and her A2 (Crush the Wall) hits about the same as Skullcrown's A2. Since she is defense-based, she is much easier to keep alive, and as an Epic, you will have books for her a lot faster than you will have them for Rathalos.
If you really want to try for a go-second team, especially as a 3v3 option, you could put one together with these toons, in this turn order:
(1) Seeker for TM Boost & Team Inc Def (Passive): A2 - A1
(2) Zelotah as aura lead (highest Epic Res Aura for Arena): A2
(3) Madame for buff strip & debuff placement: A3
- Note: If you are seeing a lot of Polymoprh, build her as a Hybrid with good Acc & Res. One of my Madames is in Untocuhable.
(4) Valla as Nuker & (back-up) Shield Removal: A2.
- Note: She hits harder with the Inc Def buff up, but depending on the setup, you may not have time to wait for the the A3 - A2 combo.
I ran a similar team in 3v3 for a very long time. It was one of my original teams that got me into G1 3v3 back in the day. Thenasil (Inc Def & Heal), Zelotah (Aura, Shields & Heal), Monster (Control, Shields, Secondary Damage) Valla (Damage).
Good Luck & Have Fun!